Material Safety Data Sheet 1. Product and company identification

Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 1 of 11
_________________________________________________________________________________________
1.
Product and company identification
Hazardous Materials
Identification System
(HMIS):
®
Product/Trade Name:
Accura ABS White (SL 7810)
System/Laser Compatibility:
For SLA systems equipped with solid-state (Nd:YVO4)
lasers
(Degree of hazard: 0 = low,
4 = extreme);
Chemical Family:
Epoxy resin containing reactive diluents
Product Use:
Material for SLA series stereolithography systems.
Health
2
Flammability
1
Physical Hazards 2
®
Personal Protection:
Manufacturer:
Skin, eye protection
Manufacturer Contact
For Information
Emergency
2.
3D Systems, Inc.
333 3D Systems Circle
Rock Hill, South Carolina 29730 U.S.A.
Toll-free Phone: 800.793.3669
800.424.9300 - Chemtrec
Hazards identification
Physical state
Odor
Color
OSHA/HCS status
:
:
:
:
Liquid
Slight
White
This material is considered hazardous by the OSHA Hazard Communication
Standard (29CFR1910.1200).
Emergency overview
:
WARNING!
CAUSES EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN
REACTION
Do not breathe vapor or mist. Do not get in eyes or on skin or clothing. Wash
thoroughly after handling.
See toxicological information (Section 11)
GENERALINFORMATION
3.
:
Read the entire MSDS for a more thorough evaluation of the hazards.
Composition/information on ingredients
Name
CAS number
%
Hydrogenated bisphenol A – epoxy resin
3-ethyloxetane-3-methanol
Propylene carbonate
Sulfonium salt mixture
Bisphenol A epoxy resin
30583-72-3
3047-32-3
108-32-7
30-60
13-30
1-3
1-3
1-3
25068-38-6
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 2 of 11
_________________________________________________________________________________________
4.
First aid measures
Eye contact
:
Check for and remove any contact lenses. Immediately flush eyes with plenty of
water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical attention immediately.
Skin contact
:
In case of contact, immediately flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing before
reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.
Inhalation
:
Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get
medical attention immediately.
Ingestion
:
Wash out mouth with water. Do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious person. Get
medical attention immediately.
Notes to physician
:
No specific treatment. Treat symptomatically. Call medical doctor or poison
control center immediately if large quantities have been ingested.
5.
Fire-fighting measures
Flash point
:
Closed cup: >95°C (>203°F) [Estimated]
Hazardous thermal
decomposition products
:
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
sulfur oxides
phosphorus oxides
halogenated compounds
Extinguishing media
Suitable
Not suitable
:
:
Use an extinguishing agent suitable for the surrounding fire.
None known.
Special exposure hazards
:
Promptly isolate the scene by removing all persons from the vicinity of the
incident if there is a fire. No action shall be taken involving any personal risk or
without suitable training.
Special protective
Equipment for fire-fighters
:
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 3 of 11
_________________________________________________________________________________________
6.
Accidental release measures
Personal precautions
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or
mist. Provide adequate ventilation. Wear appropriate respirator when ventilation
is inadequate. Put on appropriate personal protective equipment (see Section 8).
Environmental precautions
:
Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Methods for cleaning up
:
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, watercourses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain
and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according
to local regulations (see section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the
spilled product. Note: see Section 1 for emergency contact information and
Section 13 for waste disposal.
7.
Handling and storage
Handling
:
Put on appropriate personal protective equipment (see Section 8). Eating,
drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. Persons with a history of skin
sensitization problems should not be employed in any process in which this
product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid
breathing vapor or mist. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use.
Empty containers retain product residue and can be hazardous. Do not reuse
container.
Storage
:
MAXIMUM 35°C. Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and well-ventilated area,
away from incompatible materials (see section 10) and food and drink. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not
store in unlabeled containers. Use appropriate containment to avoid
environmental contamination.
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 4 of 11
_________________________________________________________________________________________
8.
Exposure controls/personal protection
Consult local authorities for acceptable exposure limits.
Recommended monitoring
procedures
:
If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the
effectiveness of the ventilation or other control measures and/or the necessity to
use respiratory protective equipment.
Engineering measures
:
No special ventilation requirements. Good general ventilation should be sufficient
to control worker exposure to airborne contaminants. If this product contains
ingredients with exposure limits, use process enclosures, local exhaust
ventilation or other engineering controls to keep worker exposure below any
recommended or statutory limits.
Hygiene measures
:
Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working
period. Appropriate techniques should be used to remove potentially
contaminated clothing. Contaminated work clothing should not be allowed out of
the workplace. Wash contaminated clothing before reusing. Ensure that eyewash
stations and safety showers are close to the work station location.
Respiratory
:
In case of inadequate ventilation wear respiratory protection. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the
product and the safe working limits of the selected respirator.
Hands
:
Chemical-resistant, impervious gloves complying with an approved standard
should be worn at all times when handling chemical products if a risk assessment
indicates this is necessary. >8 hours (break through time): Ethyl Vinyl Alcohol
Laminate (EVAL), butyl rubber.
Eyes
:
Safety eyewear complying with an approved standard should be used when a
risk assessment indicates this is necessary to avoid exposure to liquid splashes,
mists or dusts.
Skin
:
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Environmental exposure
Controls
:
Emissions from ventilation or work process equipment should be checked to
ensure they comply with the requirements of environmental protection
legislation. In some cases, fume scrubbers, filters or engineering modifications
to the process equipment will be necessary to reduce emissions to acceptable
levels.
Personal protection
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 5 of 11
_________________________________________________________________________________________
9.
Physical and chemical properties
General information
Appearance
Physical state
Color
Odor
:
:
:
Important health, safety and environmental information
pH
:
Boiling/condensation point
:
Melting/freezing point
:
Flash point
:
Flammable limits
:
Auto-ignition temperature
:
Vapor pressure
:
Specific gravity
:
Water solubility
:
Partition coefficient: n-Octanol/water (log Kow)
:
Viscosity
:
Density
:
Vapor density
:
Evaporation rate (butyl Acetate = 1)
:
VOC
:
10.
Not available.
Not available.
Not available.
Closed cup: >95°C (>203°F) [Estimated]
Not available.
Not available.
<0.14 kPa (<1.05 mm Hg) [20°C]
1.13
Slightly soluble
Not available.
Dynamic: 310 mPa·s (310 cP)
Not available.
Not available.
Not available.
Not available.
Stability and reactivity
Chemical stability
:
Hazardous polymerization :
Conditions to avoid
:
Materials to avoid
:
Hazardous decomposition
Products
:
11.
Liquid.
White.
Slight.
The product is stable.
Under normal conditions of storage and use, hazardous reactions will not occur.
Under normal conditions of storage and use, hazardous polymerization will not occur.
No specific data.
Strong acids, strong bases, strong oxidizing agents.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Toxicological information
Potential acute health effects
Inhalation
Ingestion
Skin
Eyes
Acute toxicity
Product/ingredient name
Bisphenol A epoxy resin
:
:
:
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Irritating to skin. May cause sensitization by skin contact.
Severely irritating to eyes. Risk of serious damage to eyes.
Result
LD50 Dermal
LD50 Oral
LC0 Inhalation
Vapor
Species
Rat-Male, Female
Rat-Female
Rat-Male
Dose
>2000 mg/kg
>2000 mg/kg
0.00001 ppm
Exposure
5 hours
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 6 of 11
_________________________________________________________________________________________
Chronic toxicity
Product/ingredient name
Bisphenol A epoxy resin
Result
Sub-chronic
Sub-chronic
Sub-chronic
Irritation/Corrosion
Product/ingredient name
Bisphenol A epoxy resin
Species
Rat-Male, Female
NOAEL Oral
NOEL Dermal RatMale, Female
NOAEL Dermal
Mouse-Male
Result
Skin-Mild irritant
Eyes-Mild irritant
Species
Rabbit
Rabbit
Dose
50 mg/kg
Exposure
14 weeks; 7 days per week
10 mg/kg
13 weeks; 5 days per week
100 mg/kg
13 weeks; 3 days per week
Score
-
Exposure
-
Observation
-
Skin
:
Reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number
Average molecular weight <700): Slightly irritating to the skin.
Eyes
:
Reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number
Average molecular weight <700): Slightly irritating to the eyes.
Sensitizer
Product/ingredient name
Bisphenol A epoxy resin
Route of exposure
Skin
Species
Mouse
Result
Negative-OralNOAEL
Negative-DermalNOEL
Negative-DermalNOEL
Species
Dose
Rat-Male, Female 15 mg/kg
Exposure
2 years; 7 days per week
Rat-Female
1 mg/kg
2 years; 5 days per week
Mouse-Male
0.1 mg/kg
2 years; 3 days per week
Carcinogenicity
Product/ingredient name
Bisphenol A epoxy resin
Mutagenicity
Product/ingredient name
Bisphenol A epoxy resin
Test
OECD 471 Bacterial
Reverse Mutation Test
OECD 476 In vitro
Mammalian Cell Gene
Mutation Test
OECD 478 Genetic
Toxicology: Rodent
Dominant Lethal Test
EPA OPPTS
Result
Sensitizing
Experiment
Experiment: In vitro
Subject: Bacteria
Metabolic activation: +/Experiment: In vitro
Subject: Mammalian-Animal
Cell: Somatic
Metabolic activation: +/Experiment: In vivo
Subject: MammalianAnimal
Cell: Germ
Result
Positive
Experiment: In vivo
Subject: MammalianAnimal
Cell: Somatic
Negative
Positive
Negative
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 7 of 11
_________________________________________________________________________________________
Teratogenicity
Product/ingredient name
Bisphenol A epoxy resin
Reproductive toxicity
Product/ingredient name
Bisphenol A epoxy resin
Result
Species
Negative-Oral
Rat-Female
Negative-Dermal Rabbit-Female
Negative-Oral
Rabbit-Female
12.
Exposure
10 days
13 days; 6 hours per day
13 days
Maternal Fertility Development Species Dose
toxicity
toxin
Negative Negative Negative
Rat-Male, Oral: 540
Female
mg/kg
NOEL
Potential chronic health effects
Chronic effects
:
Target organs
Carcinogenicity
Mutagenicity
Teratogenicity
Fertility effects
Developmental effects
Medical conditions
Aggravated by over-exposure
Dose
>540 mg/kg NOEL
>300 mg/kg NOEL
180 mg/kg NOAEL
Exposure
238 days; 7 days per week
:
:
:
:
:
:
Once sensitized, a severe allergic reaction may occur when subsequently
exposed to very low levels.
Not available.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Pre-existing skin disorders may be aggravated by over-exposure to this product.
Ecological information
Environmental effects
:
Aquatic ecotoxicity
Product/ingredient name
Bisphenol A epoxy resin
Test
-
Result
Acute EC50 9.4 mg/L
Fresh water
Species
Algae
Exposure
72 hours Static
OECD 202
Daphnia sp.
Acute Immobilization
Test
Acute EC50 1.7 mg/L
Fresh water
Daphnia
48 hours Static
-
Acute IC50 >100 mg/L Bacteria
Fresh water
3 hours Static
OECD 203 Fish,
Acute Toxicity Test
Acute LC50 1.5 mg/L
Fresh water
Fish
96 hours Static
OECD 211
Daphnia Magna
Reproduction Test
Chronic NOEC
0.3 mg/L
Fresh water
Daphnia
21 days Semi-static
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 8 of 11
_________________________________________________________________________________________
Biodegradability
Product/ingredient name
Bisphenol A epoxy resin
Test
OECD Derived
from OECD 301F
(Biodegradation Test)
Other ecological information
Biological Oxygen Demand (BOD 5 DAY)
Chemical Oxygen Demand (COD)
Product/ingredient name
Bisphenol A epoxy resin
Result
5%-Not readily
-28 days
:
:
Dose
20 mg/L Oxygen
consumption
Not Determined.
Not Determined
Aquatic half-life
Fresh water 4.83 days
Fresh water 3.58 days
Fresh water 7.1 days
Photolysis
-
Biodegradability
Not readily
Bioaccumulative potential
Product/ingredient name
Bisphenol A epoxy resin
LogPow
3.242
BCF
31
Potential
Low
Other adverse effects
:
No known significant effects or critical hazards.
PBT
:
Not applicable.
13.
Inoculum
-
Disposal considerations
Waste disposal
:
The generation of waste should be avoided or minimized wherever possible.
Significant quantities of waste product residues should not be disposed of via the
foul sewer but processed in a suitable effluent treatment plant. Dispose of
surplus and non-recyclable products via a licensed waste disposal contractor.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Waste packaging should be
recycled. Incineration or landfill should only be considered when recycling is not
feasible. This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product
residues. Avoid dispersal of spilled material and run off and contact with soil,
waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 9 of 11
_________________________________________________________________________________________
14.
Transport information
Proper shipping name
CFR
:
Not regulated for transport
TDG
:
Not regulated for transport
IMDG
:
Environmentally hazardous substance, liquid, n.o.s. (EPOXY RESIN) Marine pollutant
IATA
:
Environmentally hazardous substance, liquid, n.o.s. (EPOXY RESIN) Marine pollutant
Regulatory Information
IMDG Class
UN Number
UN3082
Classes
9
PG*
III
IATA-DGR Class
UN3082
9
III
Label
Additional Information
Emergency schedules (EmS) F-A, S-F
Passenger and Cargo Aircraft Quantity
limitation: 450 L
Packaging instructions: 964
Cargo Aircraft Only Quantity limitation: 450 L
Packaging instructions: 964
Remarks
***TO BE TRANSLATED***
PG*: Packing group
15.
Regulatory information
U.S. Federal regulations
HCS Classification
U.S. Federal regulations
TSCA 5(a)2 final significant
new use rule (SNUR)
TSCA 5(e) substance
consent order
TSCA 12(b) one-time
Export notification
TSCA 12(b) annual export
Notification
SARA 302/304/311/312
extremely hazardous
substances
SARA 311/312 hazard
Identification
Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)
: Irritating material
Sensitizing material
: United States inventory (TSCA 8b): All components are listed or exempted.
: None.
: None.
: None.
: None.
: SARA 302/304/311/312 extremely hazardous substances: No ingredients listed.
: SARA 311/312 MSDS distribution – chemical inventory – hazard identification:
Immediate (acute) health hazard.
: Product name
No Ingredients Listed.
CAS number
Concentration
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 10 of 11
_________________________________________________________________________________________
Clean Air Act - Ozone
Depleting Substances (ODS) : This product does not contain nor is it manufactured with ozone depleting substances.
SARA 313
: No Ingredients Listed.
CERCLA: Hazardous Substances
: No Ingredients Listed.
STATE REGULATIONS:
PENNSYLVANIA-RTK
:
California Prop 65
:
None of the components are listed.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other
reproductive harm.
Ingredient Name
Cancer
Reproductive
No significant risk level
Maximum acceptable dosage level
Toluene
No
Yes
No
7000 µg/day (ingestion)
Canada
WHMIS (Canada)
CEPA DSL
:
:
Class D-2B: Material causing other toxic effects (Toxic).
At least one component is not listed.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
International lists
16.
:
Australia inventory (AICS): At least one component is not listed.
China inventory (IECSC): At least one component is not listed.
Japan inventory: All components are listed or exempted.
Korea inventory: At least one component is not listed.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): At least one component is not listed.
Other information
Label requirements
:
CAUSES EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN
REACTION.
Hazardous Material
Information System (U.S.A.)
:
Health
Flammability
Physical Hazards
Personal Protection
2
1
2
The customer is responsible for determining the PPE code for this material.
National Fire Protection
Association (U.S.A.)
:
Flammability
1
Health
2
2
Instability
Special
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
Material Safety Data Sheet
®
Material Name: Accura ABS White (SL 7810)
Page 11 of 11
_________________________________________________________________________________________
MSDS Creation Date: .... February 7, 2012
MSDS Revision #: ......... 00-B
MSDS Revision Date: .... September 24, 2012
Reason for Revision: ..... Product Name Change
For more information: .... www.3dsystems.com
800.793.3669 (Toll-free in the US GMT-07:00; N. America, Mon – Fri, 6:00 a.m. to 6 p.m.)
+49 (0) 6151 357-357 (Europe GMT+01:00; Mon – Fri, 08:00 a.m. - 17:00 p.m. MEZ)
DISCLAIMER OF LIABILITY: The following supersedes any provision in your company’s forms, letters, and papers. 3D Systems, Inc. makes no warranty
whether expressed or implied, including warranties of merchantability or of fitness for a particular purpose for this product. No statements or
recommendations contained in the product literature are to be construed as inducements to infringe any relevant patent now or hereafter in existence.
Under no circumstances shall 3D Systems, Inc. be liable for incidental, consequential, or other damages from alleged negligence, breach of warranty,
strict liability or any other theory, arising out of the use or handling of this product. The sole liability of 3D Systems, Inc. for any claims arising out of the
manufacture, use or sale of its products shall be for the buyer’s purchase price.
© Copyright 2012 by 3D Systems, Inc. All rights reserved. Subject to change without notice. SLA, Accura and the 3D logo are registered trademarks
of 3D Systems, Inc.
Key/Legend
ACGIH = American Conference of Governmental Industrial
Hygienists
CAS = Chemical Abstracts Service
CERCLA = Comprehensive Environmental Response,
Compensation, and Liability Act
CFR = Code of Federal Regulations
CPR = Controlled Products Regulations
DOT = Department of Transportation
DSL = Domestic Substances List
EINECS = European Inventory of Existing Commercial Chemical
Substances
EPA = Environmental Protection Agency
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IDL = Ingredients Disclosure List
mg/Kg = milligrams per Kilogram
mg/L = milligrams per Liter
mg/m3 = milligrams per Cubic Meter
MSHA = Mine Safety and Health Administration
NA = Not Applicable or Not Available
NIOSH = National Institute for Occupational Safety and Health
NJTSR = New Jersey Trade Secret Registry
NTP = National Toxicology Program
OSHA = Occupational Safety and Health Administration
SARA = Superfund Amendments and Reauthorization Act
STEL = Short Term Exposure Limit
TDG = Transport Dangerous Goods
TSCA = Toxic Substances Control Act
WHMIS = Workplace Hazardous Materials Information System.
__________________________________________________________________________________________________________________________________________
®
MSDS • Accura ABS White (SL 7810) • P/N 24511-S02-00-B • ENGLISH • US
`